Find email addresses in Exchange 2010
The quickest and easiest way to work out who (or what) is using an email address is to open up a PowerShell command window and run:
get-recipient -results unlimited | where {$_.emailaddresses -match "address@company.com"} | select name,emailaddresses,recipienttype
for full details on the result, try
get-recipient -results unlimited | where {$_.emailaddresses -match "
address@company.com "} | fl